Zhibin SHA, Zhenqiang XU, Shaoying FU, Jinqiang LIANG, Wei ZHANG, Pibo SU, Hongfeng LU, Jing'an LU. Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin[J]. Marine Geology & Quaternary Geology, 2019, 39(4): 116-125. DOI: 10.16562/j.cnki.0256-1492.2019010902
Citation: Zhibin SHA, Zhenqiang XU, Shaoying FU, Jinqiang LIANG, Wei ZHANG, Pibo SU, Hongfeng LU, Jing'an LU. Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin[J]. Marine Geology & Quaternary Geology, 2019, 39(4): 116-125. DOI: 10.16562/j.cnki.0256-1492.2019010902

Gas sources and its implications for hydrate accumulation in the eastern Pearl River Mouth Basin

More Information
  • Received Date: January 08, 2019
  • Revised Date: April 10, 2019
  • Pressure cores and void gas samples are collected by drilling from target layers at five coring sites in the eastern Pearl River Mouth Basin. Dissociation gas is also sampled in thirteen layers, while headspace gas samples acquired at all the five sites. All gas samples have been tested for chemical and isotopic compositions. The gas is methane dominated, which is up to 96.5%~99.8% in concentration. Trace amount of ethane is also detected in concentration of (175~554)×10-6. No C2+ hydrocarbons have been found in all the gas samples. The isotopes of carbon and hydrogen of the methane suggest that δ13C1 is in the range of -68.4‰~-71.2‰, with δDC1 from -182‰ to -184‰, indicating a biogenic origin. The gas source of hydrate is not directly related to the occurrence of hydrate, while hydrate with multiple sources seems closely related to the evolution and morphological characteristics of reservoir. The main gas source area is located in the shallow strata less than 1000m in depth, suggesting that the hydrocarbon has migrated to the favorable stability zone to form gas hydrate accumulation by shallow lateral migration.
  • [1]
    Ginsburgc G D, Soloviev V A. Methane migration within the submarine gas-hydrate stability zone under deep-water conditions[J]. Marine Geology, 1997, 137(1-2):49-57. doi: 10.1016/S0025-3227(96)00078-3
    [2]
    Waseda A, Uchida T. Origin and migration of methane in gas hydrate-bearing sediments in the Nankai Trough[J]. The Geochemical Society Special Publications, 2004, 9: 377-387. doi: 10.1016/S1873-9881(04)80027-0
    [3]
    Choi J, Kim J H, Torres M E, et al. Gas origin and migration in the Ulleung Basin, East Sea: Results from the Second Ulleung Basin Gas Hydrate Drilling Expedition (UBGH2)[J]. Marine and Petroleum Geology, 2013, 47: 113-124. doi: 10.1016/j.marpetgeo.2013.05.022
    [4]
    Sassen R, Joye S, Sweet S Y, et al. Thermogenic gas hydrates and hydrocarbon gases in complex chemosynthetic communities, Gulf of Mexico continental slope[J]. Organic Geochemistry, 1999, 30: 485-497. doi: 10.1016/S0146-6380(99)00050-9
    [5]
    Smith A J, Mienert J, Bünz S, et al. Thermogenic methane injection via bubble transport into the upper Arctic Ocean from the hydrate-charged Vestnesa Ridge, Svalbard. Geochemistry. Geophysics[J]. Geosystems, 2014, 15(5): 1945-1959.
    [6]
    Lüdmann T, Wong H. Characteristics of gas hydrate occurrences associated with mud diapirism and gas escape structures in the northwestern Sea of Okhotsk[J]. Marine Geology, 2003, 201(4): 269-286. doi: 10.1016/S0025-3227(03)00224-X
    [7]
    Pohlman J W, Canuel E A, Chapman N R, et al. The origin of thermogenic gas hydrates on the northern Cascadia Margin as inferred from isotope (13C/12C and D/H) and molecular composition of hydrate and vent gas[J]. Organic Geochemistry, 2005, 36: 703-716. doi: 10.1016/j.orggeochem.2005.01.011
    [8]
    Vaular E N, Barth T, Haflidason H. The geochemical characteristics of the hydrate-bound gases from the Nyegga pockmark field, Norwegian Sea[J]. Organic Geochemistry, 2010, 41: 437-444. doi: 10.1016/j.orggeochem.2010.02.005
    [9]
    Lorenson T D, Collett T S. National gas hydrate expedition 01 offshore India; gas hydrate systems as revealed by hydrocarbon gas geochemistry[J]. Marine and Petroleum Geology, 2018, 92: 477-492. doi: 10.1016/j.marpetgeo.2017.11.011
    [10]
    Zhang W, Liang J Q, Lu J A, et al. Accumulation features and mechanisms of high saturation natural gas hydrate in Shenhu Area, northern South China Sea[J]. Petroleum Exploration and Development, 2017, 44(5): 708-719. doi: 10.1016/S1876-3804(17)30082-4
    [11]
    Zhang G X, Liang J Q, Lu J A, et al., Geological features, controlling factors and potential prospects of the gas hydrate occurrence in the east part of the Pearl River Mouth Basin, South China Sea[J]. Marine and Petroleum Geology, 2015, 67: 356-367. doi: 10.1016/j.marpetgeo.2015.05.021
    [12]
    Sha Z B, Liang J Q, Zhang G X, et al. Seepage gas hydrate system in northern South China Sea: Seismic and well log interpretations[J]. Marine Geology, 2015, 366:69-78. doi: 10.1016/j.margeo.2015.04.006
    [13]
    刘昌岭, 李彦龙, 孙建业, 等.天然气水合物试采:从实验模拟到现场实施[J].海洋地质与第四纪地质, 2017, 37(5):12-26. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=9b7fce26-e41f-477d-b3bb-bb3197a94ec3

    LIU Changling, LI Yanlong, SUN Jianye, et al.Gas hydrate production test: From experimental simulation to filed practice[J]. Marine Geology & Quaternary Geology, 2017, 37(5):12-26. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=9b7fce26-e41f-477d-b3bb-bb3197a94ec3
    [14]
    王力峰, 尚久靖, 梁金强, 等.南海东北部陆坡水合物钻探区海底表层热导率分布特征[J].海洋地质与第四纪地质, 2016, 36(2):29-37. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=79ff973e-9a4c-4288-bc4b-efe292faa918

    WANG Lifeng, SHANG Jiujing, LIANG Jinqiang, et al. Distribution pattern of seafloor thermal conductivities at the drilling area for gas hydrate on the northeastern slope of South China Sea[J]. Marine Geology & Quaternary Geology, 2016, 36(2):29-37. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=79ff973e-9a4c-4288-bc4b-efe292faa918
    [15]
    沙志彬, 梁金强, 苏丕波, 等.珠江口盆地东部海域天然气水合物钻探结果及其成藏要素研究[J].地学前缘, 2015, 22(6):125-135. http://d.old.wanfangdata.com.cn/Periodical/dxqy201506009

    SHA Zhibin, LIANG Jinqiang, SU Pibo, et al. Natural gas hydrate accumulation elements and drilling results analysis in the eastern part of the Pearl River Mouth Basin[J]. Earth Science Frontiers, 2015, 22(6):125-135. http://d.old.wanfangdata.com.cn/Periodical/dxqy201506009
    [16]
    施和生, 何敏, 张丽丽, 等.珠江口盆地(东部)油气地质特征、成藏规律及下一步勘探策略[J].中国海上油气, 2014, 26 (3):11-22. http://d.old.wanfangdata.com.cn/Periodical/zghsyq-gc201403002

    SHI Hesheng, HE Min, ZHANG Lili, et al. Hydrocarbon geology, accumulation pattern and the next exploration strategy in the eastern Pearl River Mouth Basin[J]. China Offshore Oil and Gas, 2014, 26 (3):11-22. http://d.old.wanfangdata.com.cn/Periodical/zghsyq-gc201403002
    [17]
    何家雄, 刘海龄, 姚永坚, 等.南海北部边缘盆地油气地质及资源前景[M].北京:石油工业出版社, 2008.

    HE Jiaxiong, LIU Hailing, YAO Yongjian, et al.The Petroleum Geology and the Resource Potential of the Marginal Basins in the Northern South China Sea[M]. Beijing: Petroleum Industry Press, 2008.
    [18]
    梁金强, 付少英, 陈芳, 等.南海东北部陆坡海底甲烷渗漏及水合物成藏特征[J].天然气地球科学, 2017, 28(5):761-770. http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201705011

    LIANG Jinqiang, FU Shaoying, CHEN Fang, et al. Characteristics of methane seepage and gas hydrate reservoir in the northeastern slope of South China Sea[J]. Natural Gas Geoscience, 2017, 28(5):761-770. http://d.old.wanfangdata.com.cn/Periodical/trqdqkx201705011
    [19]
    王秀娟, 吴时国, 刘学伟, 等.东沙海域天然气水合物特征分析及饱和度估算[J].石油物探, 2009, 48 (5):445-452. doi: 10.3969/j.issn.1000-1441.2009.05.003

    WANG Xiujuan, WU Shiguo, LIU Xuewei, et al. Characteristic analysis and saturation estimation of gas hydrate in Dongsha sea area[J]. Geophysical Prospecting for Petroleum, 2009, 48 (5):445-452. doi: 10.3969/j.issn.1000-1441.2009.05.003
    [20]
    Youhai Z, Xia H, Shaoying F, et al. Gas sources of natural gas hydrates in the Shenhu Drilling Area, South China Sea: geochemical evidence and geological analysis[J]. Acta Geologica Sinica (English Edition), 2013, 87(3): 767-776. doi: 10.1111/1755-6724.12088
    [21]
    黄霞, 祝有海, 卢振权, 等.南海北部天然气水合物钻探区烃类气体成因类型研究[J].现代地质, 2010, 24(3):576-580. doi: 10.3969/j.issn.1000-8527.2010.03.023

    HUANG Xia, ZHU Youhai, LU Zhenquan, et al. Study on genetic types of hydrocarbon gases from the gas hydrate drilling area, the northern South China Sea[J]. Geoscience, 2010, 24(3):576-580. doi: 10.3969/j.issn.1000-8527.2010.03.023
    [22]
    丛晓荣, 苏明, 吴能友, 等.富生烃凹陷背景下热成因气对水合物成藏贡献的探讨[J].地质学报, 2018, 92(1):170-183. doi: 10.3969/j.issn.0001-5717.2018.01.012

    CONG Xiaorong, SU Ming, WU Nengyou, et al. Contribution of thermogenic gases to hydrate accumulation under the marine hydrocarbon-rich depression setting[J]. Acta Geologica Sinica, 2018, 92(1):170-183. doi: 10.3969/j.issn.0001-5717.2018.01.012
    [23]
    Whiticar M J, Faber E, Schoell M. Biogenic methane formation in marine and freshwater environments: CO2 reduction VS. acetate fermentation-isotope evidence[J]. Geochimica et Cosmochimica Acta, 1986, 50: 693-709. doi: 10.1016/0016-7037(86)90346-7
    [24]
    李先奇, 张水昌, 朱光有, 等.中国生物成因气的类型划分与研究方向[J].天然气地球科学, 2005, 16(4):477-484. doi: 10.3969/j.issn.1672-1926.2005.04.015

    LI Xianqi, ZHANG Shuichang, ZHU Guangyou, et al. Types and research direction of biogenic gas in China[J]. Natural Gas Geoscience, 2005, 16(4):477-484. doi: 10.3969/j.issn.1672-1926.2005.04.015
    [25]
    张水昌, 赵文智, 李先奇, 等.生物气研究新进展与勘探策略[J].石油勘探与开发, 2005, 32 (4):90-96. doi: 10.3321/j.issn:1000-0747.2005.04.015

    ZHANG Shuichang, ZHAO Wenzhi, LI Xianqi, et al. Advances in biogenic gas studies and play strategies[J]. Petroleum Exploration and Development, 2005, 32 (4):90-96. doi: 10.3321/j.issn:1000-0747.2005.04.015
    [26]
    Bernard B, Brooks J M, Sackett W M. A geochemical model for characterization of hydrocarbon gas sources in marine sediments[C]//Offshore Technology Conference. 1977.
    [27]
    Whiticar M J. Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane[J]. Chemical Geology, 1999, 161(1-3): 291-314. doi: 10.1016/S0009-2541(99)00092-3
    [28]
    Matsumoto R, Takashi U, Waseda A, et al. Occurrence, structure, and composition of natural gas hydrate recovered from the Blake Ridge, Northwest Atlantic[R]//Proceedings of the Ocean Drilling Program Scientific Results. 2000, 164: 13-28.
    [29]
    毕海波, 马立杰, 黄海军, 等.台西南盆地天然气水合物甲烷量估算[J].海洋地质与第四纪地质, 2010, 30(4):179-186. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=ac391bbe-2dd5-42b2-adb0-6716a0182054

    BI Haibo, MA Lijie, HUANG Haijun, et al. Estimation of methane amount contained in gas hydrate in Taixi'nan Basin based on GIS[J]. Marine Geology & Quaternary Geology, 2010, 30(4):179-186. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=ac391bbe-2dd5-42b2-adb0-6716a0182054
    [30]
    Ye J L, Qin X W, Qiu H J, et al. Data Report: Molecular and Isotopic composition of the extracted gas from China's first offshore national gas hydrate production test in South China Sea[J]. Energies, 2018, 11(10): 2793. doi: 10.3390/en11102793
    [31]
    毕海波.台西南海域天然气水合物含量估算及地球化学特征分析[D].中国科学院海洋研究所, 2010. http://cdmd.cnki.com.cn/article/cdmd-80068-2010147972.htm

    BI Haibo. Amount estimation and geochemical analysis of gas hydrate of Tai Xi Nan Basin[D]. Institute of Oceanology, Chinese Academy of Sciences, 2010. http://cdmd.cnki.com.cn/article/cdmd-80068-2010147972.htm
    [32]
    何家雄, 颜文, 祝有海, 等.全球天然气水合物成矿气体成因类型及气源构成与主控因素[J].海洋地质与第四纪地质, 2013, 33(2):121-128. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=7a4605af-01b9-4cf2-a35d-a1fdb79d75e6

    HE Jiaxiong, YAN Wen, ZHU Youhai, et al. Genetic types of gas hydrate in the word and their main controlling factors[J]. Marine Geology & Quaternary Geology, 2013, 33(2):121-128. http://hydz.chinajournal.net.cn/WKD/WebPublication/paperDigest.aspx?paperID=7a4605af-01b9-4cf2-a35d-a1fdb79d75e6
    [33]
    邬黛黛.南海天然气水合物的早期成岩作用和地球化学特性研究[D].浙江大学, 2008. http://cdmd.cnki.com.cn/Article/CDMD-10335-2009024630.htm

    WU Daidai. Early diagenesis records and geochemical characteritics of gas hydrate in the South China Sea[D]. Zhejiang University, 2008. http://cdmd.cnki.com.cn/Article/CDMD-10335-2009024630.htm

Catalog

    Article views (3031) PDF downloads (55) Cited by()

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return