Rare earth element geochemistry of the sediments from small rivers draining southeast China

GUO Yulong; YANG Shouye; SU Ni; YIN Ping; WANG Zhongbo

doi:10.16562/j.cnki.0256-1492.2018.01.014

Marine Geology & Quaternary Geology > 2018 > 38(1): 139-149. > DOI: 10.16562/j.cnki.0256-1492.2018.01.014

GUO Yulong, YANG Shouye, SU Ni, YIN Ping, WANG Zhongbo. Rare earth element geochemistry of the sediments from small rivers draining southeast China[J]. Marine Geology & Quaternary Geology, 2018, 38(1): 139-149. DOI: 10.16562/j.cnki.0256-1492.2018.01.014

Citation:

PDF (4829 KB)

Rare earth element geochemistry of the sediments from small rivers draining southeast China

1.
State Key Laboratory of Marine Geology, Shanghai 200092, China
2.
Laboratory for Marine Geology and Enviroment, Qingdao National Laboratory for Marine Science and Technology, Qingdao 266061, China
3.
Qingdao Institute of Marine Geology, CGS, Qingdao 266071, China

More Information

Received Date: May 30, 2017
Revised Date: December 20, 2017

Graphical Abstract

Abstract

Abstract

Representative suspended and floodplain sediment samples were systematically collected from three small rivers in Zhejiang and Fujian provinces. Two chemical phases (leachates and residues) were separated by 1N HCl leaching and the leachates account for 32%~82% of the total REE concentration. The absorption on Mn-Fe (hydro)oxides and clay minerals are the main hosts of acid-leachable REEs. The REE compositions of the leachates can potentially indicate the whole weathering history of the sediments to some extent. Silicate minerals and stable heavy minerals like zircon are important hosts of residual REEs, and the residual fractions are reliable for the indication of sediment provenance. The weathering products of river basins and Changjiang-derived sediments pumped by strong tide into the estuaries are the main sources of these rivers sediments. REE fractionation is demonstrated during extreme chemical weathering and hydrodynamic sorting processes, and thus it should be cautious to use the bulk REE compositions of these river sediments to indicate the sediment provenance. Slight positive Gd anomalies occur both in the leachates and residues, which do not indicate the presence of anthropogenic Gd, but reflect the geochemical compositions of the materials in Eastern China.
- small rivers,
- rare earth elements,
- sediment,
- provenance study

FullText(HTML)

References (37)

References

[1]	Bayon G, Toucanne S, Skonieczny C, et al. Rare earth elements and neodymium isotopes in world river sediments revisited[J]. Geochimica et Cosmochimica Acta, 2015, 170: 17-38. doi: 10.1016/j.gca.2015.08.001
[2]	Singh P. Major, trace and REE geochemistry of the Ganga River sediments: Influence of provenance and sedimentary processes[J]. Chemical Geology, 2009, 266(3-4): 242-255. doi: 10.1016/j.chemgeo.2009.06.013
[3]	Taylor S R, McLennan S M. The Continental Crust: Its Composition and Evolution-An Examination of the Geochemical Record Preserved in Sedimentary Rocks[M]. Blackwell Oxford: Scientific Pub., 1985.
[4]	杨守业, 王中波.长江主要支流与干流沉积物的REE组成[J].矿物岩石地球化学通报, 2011, 30(1): 31-39. doi: 10.3969/j.issn.1007-2802.2011.01.005 YANG Shouye, WANG Zhongbo. Rare earth element compositions of the sediments from the major tributaries and the main stream of the Changjiang river[J]. Bulletin of Mineralogy, Petrology and Geochemistry, 2011, 30(1): 31-39. doi: 10.3969/j.issn.1007-2802.2011.01.005
[5]	杨守业, 韦刚健, 夏小平, 等.长江口晚新生代沉积物的物源研究: REE和Nd同位素制约[J].第四纪研究, 2007, 27(3): 339-346. doi: 10.3321/j.issn:1001-7410.2007.03.005 YANG Shouye, WEI Gangjian, XIA Xiaoping, et al. Provenance study of the Late Cenozoic sediments in the Changjiang delta: REE and Nd isotopic constraints[J]. Quaternary Sciences, 2007, 27(3): 339-346. doi: 10.3321/j.issn:1001-7410.2007.03.005
[6]	Yang S Y, Jung H S, Man S C, et al. The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments[J]. Earth & Planetary Science Letters, 2002, 201(2): 407-419. http://www.wanfangdata.com.cn/details/detail.do?_type=perio&id=7b6a25c53b1771b07dc62a038ae469e1
[7]	Zhang C S, Wang L J. Multi-element geochemistry of sediments from the Pearl River system, China[J]. Applied Geochemistry, 2001, 16(9-10): 1251-1259. doi: 10.1016/S0883-2927(01)00007-5
[8]	乔淑卿, 杨作升.长江和黄河入海沉积物不同粒级组分中稀土元素的比较[J].海洋地质与第四纪地质, 2007, 27(6): 9-16. http://www.cnki.com.cn/Article/CJFDTotal-HYDZ200706004.htm QIAO Shuqing, YANG Zuosheng. Comparison of rare earth element compositions in different grain-size fractions of sediments from the Yangtze and Yellow Rivers to the sea[J]. Maine Geology and Quaternary Geology, 2007, 27(6): 9-16. http://www.cnki.com.cn/Article/CJFDTotal-HYDZ200706004.htm
[9]	杨守业, 李超, 王中波, 等.现代长江沉积物地球化学组成的不均一性与物源示踪[J].第四纪研究, 2013, 33(4): 645-655. doi: 10.3969/j.issn.1001-7410.2013.04.03 YANG Shouye, LI Chao, WANG Zhongbo, et al. Heterogeneity of geochemical compositions of the Changjiang River sediments and provenance indication[J]. Quaternary Sciences, 2013, 33(4): 645-655. doi: 10.3969/j.issn.1001-7410.2013.04.03
[10]	Su N, Yang S Y, Guo Y L, et al. Revisit of rare earth element fractionation during chemical weathering and river sediment transport[J]. Geochemistry, Geophysics, Geosystems, 2017, 18(3): 935-955. doi: 10.1002/2016GC006659
[11]	周国华, 孙彬彬, 刘占元, 等.中国东部主要河流稀土元素地球化学特征[J].现代地质, 2012, 26(5): 1028-1042. doi: 10.3969/j.issn.1000-8527.2012.05.024 ZHOU Guohua, SUN Binbin, LIU Zhanyuan, et al. Geochemical feature of rare earth elements in major rivers of Eastern China[J]. Geoscience, 2012, 26(5): 1028-1042. doi: 10.3969/j.issn.1000-8527.2012.05.024
[12]	Garzanti E, Andó S, France-Lanord C, et al. Mineralogical and chemical variability of fluvial sediments 2. Suspended-load silt (Ganga-Brahmaputra, Bangladesh)[J]. Earth and Planetary Science Letters, 2011, 302(1-2): 107-120. doi: 10.1016/j.epsl.2010.11.043
[13]	Kulaksız S, Bau M. Contrasting behaviour of anthropogenic gadolinium and natural rare earth elements in estuaries and the gadolinium input into the North Sea[J]. Earth and Planetary Science Letters, 2007, 260(1-2): 361-371. doi: 10.1016/j.epsl.2007.06.016
[14]	Marchandise S, Robin E, Ayrault S, et al. U-Th-REE-Hf bearing phases in Mediterranean Sea sediments: Implications for isotope systematics in the ocean[J]. Geochimica et Cosmochimica Acta, 2014, 131: 47-61. doi: 10.1016/j.gca.2014.01.017
[15]	Nesbitt H W, Macrae N D, Kronberg B I. Amazon deep-sea fan muds: light REE enriched products of extreme chemical weathering[J]. Earth and Planetary Science Letters, 1990, 100(1-3): 118-123. doi: 10.1016/0012-821X(90)90180-6
[16]	Nesbitt H W. Mobility and fractionation of rare earth elements during weathering of a granodiorite[J]. Nature, 1979, 279(5710): 206-210. doi: 10.1038/279206a0
[17]	Condie K C, Dengate J, Cullers R L. Behavior of rare earth elements in a paleoweathering profile on granodiorite in the Front Range, Colorado, USA[J]. Geochimica et Cosmochimica Acta, 1995, 59(2): 279-294. doi: 10.1016/0016-7037(94)00280-Y
[18]	Harlavan Y, Erel Y. The release of Pb and REE from granitoids by the dissolution of accessory phases[J]. Geochimica et Cosmochimica Acta, 2002, 66(5): 837-848. doi: 10.1016/S0016-7037(01)00806-7
[19]	Milliman J D, Farnsworth K L. River discharge to the coastal ocean: a global synthesis[D]. Cambridge: Cambridge University Press, 2011.
[20]	Zhang J, Liu C L. Riverine composition and estuarine geochemistry of particulate metals in China-weathering features, anthropogenic impact and chemical fluxes[J]. Estuarine Coastal and Shelf Science, 2002, 54(6): 1051-1070. doi: 10.1006/ecss.2001.0879
[21]	徐海, 李伯根.椒江河口洪季最大浑浊带核部的悬沙分选机制[J].海洋通报, 2009, 28(5): 64-73. doi: 10.3969/j.issn.1001-6392.2009.05.010 XU Hai, LI Bogen. Size distribution of suspended sediment in nucleus band of turbidity maximum of Jiaojiang River Estuary in wet season[J]. Marine Science Bulletin, 2009, 28(5): 64-73. doi: 10.3969/j.issn.1001-6392.2009.05.010
[22]	马丽芳.中国地质图集[M].北京:地质出版社, 2002. MA Lifang. Atlas of China Geology[M]. Beijing: Geological Publishing House, 2002.
[23]	李兼海.全国地层多重划分对比研究:福建省岩石地层[M].武汉:中国地质大学出版社, 1997. LI Jianhai. Comparison of National Stratigraphic Multiple Division, Fujian Lithostratigraphic. Fujian Provincial Bureau of Geology and Mineral Resources[M]. Wuhan: China University of Geosciences Press, 1997.
[24]	俞国华.浙江省岩石地层[M].武汉:中国地质大学出版社, 1996. YU Guohua. Stratigraphy (Lithostratic) of Zhejiang Provence[M]. Wuhan: China University of Geosciences Press, 1996.
[25]	Dou Y, Yang S, Liu Z, et al. Provenance discrimination of siliciclastic sediments in the middle Okinawa Trough since 30 ka: Constraints from rare earth element compositions[J]. Marine Geology, 2010, 275(1-4): 212-220. doi: 10.1016/j.margeo.2010.06.002
[26]	陈骏, 王洪涛, 鹿化煜.陕西洛川黄土沉积物中稀土元素及其它微量元素的化学淋滤研究[J].地质学报, 1996, 70(1): 61-72. doi: 10.1088-1751-8113-43-43-434001/ CHEN Jun, WANG Hongtao, LU Huayu. Behaviors of REE and other trace elements during pedological weathering-Evidence from chemical leaching of loess and paleosol from the Luochuan section in central China[J]. Acta Geological Sinica, 1996, 70(1): 61-72. doi: 10.1088-1751-8113-43-43-434001/
[27]	Rudnick R L, Gao S. Composition of the continental crust[M]//Holland H D, Turekian K K, Eds. Treatise on Geochemistry. Oxford: Elsevier-Pergamon, 2003: 1-64.
[28]	Bi L, Yang S Y, Li C, et al. Geochemistry of river-borne clays entering the East China Sea indicates two contrasting types of weathering and sediment transport processes[J]. Geochemistry, Geophysics, Geosystems, 2015, 16(9): 3034-3052. doi: 10.1002/2015GC005867
[29]	Nesbitt H W, Young G M. Early proterozoic climates and plate motions inferred from major element chemistry of lutites[J]. Nature, 1982, 299(5885): 715-717. doi: 10.1038/299715a0
[30]	Bayon G, German C R, Burton K W, et al. Sedimentary Fe-Mn oxyhydroxides as paleoceanographic archives and the role of aeolian flux in regulating oceanic dissolved REE[J]. Earth and Planetary Science Letters, 2004, 224(3-4): 477-492. doi: 10.1016/j.epsl.2004.05.033
[31]	Freslon N, Bayon G, Toucanne S, et al. Rare earth elements and neodymium isotopes in sedimentary organic matter[J]. Geochimica et Cosmochimica Acta, 2014, 140: 177-198. doi: 10.1016/j.gca.2014.05.016
[32]	Yang S Y, Jung H S, Li C X. Two unique weathering regimes in the Changjiang and Huanghe drainage basins: geochemical evidence from river sediments[J]. Sedimentary Geology, 2004, 164(1-2): 19-34. doi: 10.1016/j.sedgeo.2003.08.001
[33]	Hermann J, Rubatto D. Accessory phase control on the trace element signature of sediment melts in subduction zones[J]. Chemical Geology, 2009, 265(3-4): 512-526. doi: 10.1016/j.chemgeo.2009.05.018
[34]	迟清华, 鄢明才.应用地球化学元素丰度数据手册[M].北京:地质出版社, 2007. CHI Qinghua, YAN Mingcai. Handbook of Elemental Abundance for Apploed Geochemistry[M]. Beijing: Geological Publishing House, 2007.
[35]	Viers J, Dupré B, Gaillardet J. Chemical composition of suspended sediments in world rivers: New insights from a new database[J]. Science of the Total Environment, 2009, 407(2): 853-868. doi: 10.1016/j.scitotenv.2008.09.053
[36]	Bau M, Dulski P. Anthropogenic origin of positive gadolinium anomalies in river waters[J]. Earth and Planetary Science Letters, 1996, 143(1-4): 245-255. doi: 10.1016/0012-821X(96)00127-6
[37]	VJohannesson K H, Hawkins Jr D L, Cortés A. Do Archean chemical sediments record ancient seawater rare earth element patterns?[J]. Geochimica et Cosmochimica Acta, 2006, 70(4): 871-890. doi: 10.1016/j.gca.2005.10.013

[1]	ZHAO Zhuxu, XIONG Wei, WANG Zhonglei, HUANG Long, MI Beibei, WANG Jun, MEI Xi. Distribution and origination of rare earth elements in surface sediments of the Bohai Strait[J]. Marine Geology & Quaternary Geology, 2024, 44(5): 151-160. DOI: 10.16562/j.cnki.0256-1492.2024072501
[2]	MI Beibei, ZHANG Yong, MEI Xi, WANG Zhonglei, DOU Yanguang. Distribution of rare earth elements in surface sediments of the South Yellow Sea and its implication to sediment provenances[J]. Marine Geology & Quaternary Geology, 2022, 42(6): 93-103. DOI: 10.16562/j.cnki.0256-1492.2022072901
[3]	QI Wenjing, LI Xiaoyan, FAN Dejiang, ZHANG Hui, YIN Zhengxin, LIU Shengfa. Rare earth element composition of the surface sediments from the Ninetyeast Ridge and its implications for provenance[J]. Marine Geology & Quaternary Geology, 2022, 42(2): 92-100. DOI: 10.16562/j.cnki.0256-1492.2021050701
[4]	WANG Yueqi, SONG Jinming, YUAN Huamao, LI Xuegang, LI Ning, WANG Qidong. Variation in rare earth elements and provenances of the sediments along the Kuroshio mainstream to the east of Taiwan over the past millennium[J]. Marine Geology & Quaternary Geology, 2019, 39(2): 104-113. DOI: 10.16562/j.cnki.0256-1492.2018041601
[5]	HU Siyi, ZENG Zhigang, YIN Xuebo, ZHU Bowen, FANG Xue, QI Haiyan. Characteristics of rare earth elements in the sediment cores from the Okinawa Trough and their implications for sediment provenance[J]. Marine Geology & Quaternary Geology, 2019, 39(1): 69-82. DOI: 10.16562/j.cnki.0256-1492.2017082301
[6]	SU Ni, BI Lei, GUO Yulong, YANG Shouye. Rare earth element compositions and provenance implications:A case from sediments of the Mulanxi River Estuary and surrounding sea area[J]. Marine Geology & Quaternary Geology, 2018, 38(1): 150-159. DOI: 10.16562/j.cnki.0256-1492.2018.01.015
[7]	CHU Zheng, HU Ningjing, LIU Jihua, GAO Jianfeng, ZHU Aimei, GAO Jingjing, ZHANG Hui. RARE EARTH ELEMENTS IN SEDIMENTS OF WEST PHILIPPINE SEA AND THEIR IMPLICATIONS FOR SEDIMENT PROVENANCE[J]. Marine Geology & Quaternary Geology, 2016, 36(5): 53-62. DOI: 10.16562/j.cnki.0256-1492.2016.05.006
[8]	FU Piaoer, ZHUANG Chang, LIU Jian, CHEN Daohua, ZHANG Xin, CHEN Sihai. RARE EARTH ELEMENTS GEOCHEMISTRY AND PROVENANCE OF THE SEDIMENTS FROM CORE XH-CL16 IN THE XISHA TROUGH, SOUTH CHINA SEA[J]. Marine Geology & Quaternary Geology, 2015, 35(4): 63-71. DOI: 10.16562/j.cnki.0256-1492.2015.04.007
[9]	CHEN Zhihua, HUANG Yuanhui, TANG Zheng, WANG Haozhuang, GE Shulan, FANG Xisheng, HAN Xibin, WANG Aijun, WU Li, ZHU Zhimin. RARE EARTH ELEMENTS IN THE OFFSHORE SURFACE SEDIMENTS OF THE NORTHEASTERN ANTARCTIC PENINSULA AND THEIR IMPLICATIONS FOR PROVENANCE[J]. Marine Geology & Quaternary Geology, 2015, 35(3): 145-155. DOI: 10.3724/SP.J.1140.2015.03145
[10]	XU Gang, LIU Jian, KONG Xianghuai, ZHANG Junqiang, QIU Jiandong. RARE EARTH ELEMENTS IN SURFACE SEDIMENTS OF WESTERN SOUTH YELLOW SEA AND THEIR PROVENANCE IMPLICATIONS[J]. Marine Geology & Quaternary Geology, 2012, 32(1): 11-17. DOI: 10.3724/SP.J.1140.2012.01011

Cited By

Get Citation

PDF

XML

Article views (3240) PDF downloads (56)

Turn off MathJax

Article Contents

Abstract

References

Rare earth element geochemistry of the sediments from small rivers draining southeast China

Abstract

References

Related Articles

Catalog

Links

About Journal

Contact Us

Rare earth element geochemistry of the sediments from small rivers draining southeast China

Abstract

References

Related Articles

Catalog

Links

About Journal

Contact Us

Export File

Citation

Format

Content