昆明地区不同基岩红土矿物组成及微量元素的指示意义研究

The indicative significance of mineral composition and trace elements in laterite of different bedrocks in Kunming area

  • 摘要: 我国南方广泛发育不同类型的红土,但西南地区的红土与华南地区有明显的差别。基于昆明地区不同基岩发育的红土剖面,包括灰岩(JC剖面)、砂岩(NL剖面)、玄武岩(XTC剖面)和泥岩(LHX剖面),通过矿物、微量元素以及元素与矿物的相关性,获取了昆明地区红土风化特征、微量元素富集和亏损及其与矿物相关性的认识。①不同基岩的红土主要矿物为石英、长石、黏土矿物、三水铝石、针铁矿和赤铁矿,不同基岩红土整体上风化程度较高,但风化早期的黏土矿物伊利石、绿泥石和风化晚期的高岭石和三水铝石并存是昆明地区红土的特色,可能与高原的气候环境特征有关。②不同基岩红土的微量元素质量迁移系数显示灰岩和砂岩风化程度较高,属于残积型红土;玄武岩红土风化程度亦高,但微量元素质量迁移系数偏正,指示其为母岩继承型;泥岩红土的风化程度相对较弱,质量迁移系数基本为正值,属于母岩继承型。③微量元素与矿物的相关性表明,灰岩和砂岩红土中微量元素相对母岩富集程度较高,三水铝石和高岭石对Cu、Ni等微量元素吸附作用导致其富集;玄武岩红土三水铝石和高岭石对微量元素的富集作用也较强。不同基岩红土微量元素Rb与黏土矿物的相关性并不一致,其变化受含K矿物和黏土矿物的两种因素控制。矿物组成和微量元素的特征揭示出不同基岩红土风化强度的差异。

     

    Abstract: Different types of laterites are widely developed in South China, but the laterite in the SW China is significantly different from that in South China. Based on the laterite sections on different bedrocks in the Kunming area, Yunnan, including limestone (JC Section), sandstone (NL Section), basalt (XTC Section), and mudstone (LHX Section),insights into the weathering characteristics of laterite, the enrichment and depletion of trace elements, and their correlations with minerals in the Kunming area were obtained by analyzing minerals, trace elements, and the correlations between elements and minerals. ① The main minerals of laterite from different parent rocks are quartz, feldspar, clay minerals, gibbsite, goethite, and hematite, and the overall weathering degree of the laterites is relatively high. However, the coexistence of early-weathered clay minerals such as illite and chlorite and lately-weathered kaolinite and gibbsite is the characteristics of the laterites, which may be related to the climatic and environmental characteristics of the plateau reguon. ② The mass transfer coefficients (MTE) of trace elements in the laterite show that the weathering degree of the laterite developed from limestone and sandstone is relatively high, belonging to residual laterite; the weathering degree of basalt-originated laterite is also high, but the MTE of trace elements is positive, indicating that it is inherited from the parent rock; the weathering degree of mudstone-originated laterite is relatively weak, and the MTE is largely positive, belonging to the inheritance of the parent rock too. ③ The correlation between trace elements and minerals indicates that the enrichment degree of trace elements in the laterite of limestone and sandstone in origin is relatively high, and the adsorption of Cu, Ni, and other trace elements by gibbsite and kaolinite leads to their enrichment; the enrichment effect of trace elements by gibbsite and kaolinite in basalt laterite is also strong. The correlation between Rb and clay minerals in the laterite is not consistent, and its variation is controlled by two factors: K-bearing minerals and clay minerals. The characteristics of mineral composition and trace elements reveal the differences in weathering intensity of laterite developed from different parent rocks.

     

/

返回文章
返回