冲绳海槽中北段海底冷泉活动岩石记录与过程研究

Records and analyses of submarine cold seep activity in the middle and northern Okinawa Trough

  • 摘要: 冷泉碳酸盐岩是保存冷泉活动和海洋沉积环境信息的可靠地质档案,其矿物和元素特征可以有效保存过去冷泉活跃时期流体来源和组成、渗漏强度及氧化还原条件等信息。中国东海冲绳海槽广泛发育冷泉,然而,该海域目前对冷泉碳酸盐岩记录的活跃时期环境变化的了解还不充分。本研究以冲绳海槽中北段“观山”冷泉活跃区碳酸盐岩结壳为研究对象,系统开展了矿物学、元素和同位素地球化学研究,旨在揭示研究区冷泉碳酸盐岩形成时的环境条件。研究发现,该冷泉碳酸盐岩结壳主要由文石(平均含量58.3%)组成,所有碳酸盐岩样本均具有δ13C中等偏负(–40.4‰~ –28.4‰)、δ18O高度富集(4.0‰~5.8‰)的特征,指示冷泉碳酸盐岩的碳源为热成因甲烷,且研究区甲烷渗漏通量较大。“观山”区冷泉碳酸盐岩形成是由靠近海底硫酸盐驱动的甲烷厌氧氧化作用(SD-AOM)所致。天然气水合物的分解增强了冷泉活动,导致自生碳酸盐岩矿物形成于海底浅层相对氧化的环境中。稳定碳、氧同位素以及稀土元素配分模式等地球化学指标,为建立不同类型冷泉碳酸盐岩的形成模式提供了重要的参考依据。

     

    Abstract: Cold-seep carbonates serve as reliable geological archives that preserve critical information on seepage activity and paleo-marine sedimentary environments. Their mineralogical and geochemical characteristics effectively record fluid sources and composition, seepage intensity, and redox conditions during past periods of active seepage. Although cold seeps are widely distributed in the Okinawa Trough of the East China Sea, the relationship between carbonate records and paleoenvironmental changes during past active periods in this region remains poorly understood. This study focuses on carbonate crusts from the active “Guanshan” seep site in the middle and northern Okinawa Trough, employing systematic mineralogical, elemental, and isotopic geochemical analyses to elucidate the environmental conditions during carbonate formation. The results demonstrate that the cold-seep carbonate crusts are predominantly composed of aragonite (average 58.3%). All samples exhibit moderately negative δ13C values (–40.4‰ to –28.4‰) coupled with highly enriched δ18O signatures (+4.0‰ to +5.8‰), indicating a thermogenic methane source and relatively high methane flux in the study area. The formation of Guanshan cold-seep carbonates was primarily driven by sulfate-driven anaerobic oxidation of methane (SD-AOM) near the seafloor, with gas hydrate dissociation likely enhancing seepage activity. These carbonates precipitated in a relatively oxic, shallow subsurface environment. Measurements of carbon and oxygen isotopes (δ13C, δ18O), coupled with rare earth element (REE) patterns, provide key constraints on the formation models of distinct cold seep carbonates.

     

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