西藏申扎地区下二叠统冷泉碳酸盐岩的地球化学特征

Geochemical characteristics of Lower Permian cold seep carbonate rocks in Xainza, Xizang (Tibet), China

  • 摘要: 冷泉碳酸盐岩作为冷泉流体活动的最重要的产物之一,其地球化学信息对于揭示冷泉系统演化、流体来源以及冷泉碳酸盐岩形成时的氧化还原环境具有重要意义。本研究以中国西藏申扎地区下二叠统古冷泉碳酸盐岩为研究对象,通过岩石学和矿物学、碳氧同位素和稀土元素地球化学研究,探讨其流体来源和形成时的氧化还原环境。研究结果显示,该地区冷泉碳酸盐岩以方解石为主,δ13C值为−19.6‰~−17.5‰,δ18O值为−9.2‰~−7.2‰,指示冷泉碳酸盐岩的碳源以热成因甲烷为主,可能还受到少量海水的混合作用影响。稀土元素配分模式呈现“钟型”特征,Ce轻微异常,指示冷泉碳酸盐岩形成于弱氧化或还原的环境。

     

    Abstract: Cold seep carbonates are one of the most important products of cold seep fluid activity. Their geochemical information is of great significance for revealing the evolution of cold seep systems, the source of fluids, and the redox environment when cold seep carbonates were formed. Taking the paleo-cold seep carbonates of the Lower Permian in Xainza, Xizang (Tibet), SW China as the research object, we explored their fluid sources and sedimentary environments in petrology, mineralogy, carbon and oxygen isotopes, and rare earth element geochemistry. Results show that the cold seep carbonates in the region are mainly calcite, whose δ13C values ranged from -19.6‰ to -17.5‰, and δ18O values from -9.2‰ to -7.2‰, indicating that the carbon source of the cold seep carbonates was mainly from thermogenic methane and was also affected by the mixing of a small amount of seawater. The rare earth element distribution pattern shows a “bell-shaped” feature with a slight anomaly of Ce, indicating that the cold seep carbonates were deposited in a weakly oxidizing or reducing environment.

     

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